How do multiple people receive email notifications for new purchase orders?

You can list up to five separate email addresses in your Electronic Order Routing preferences. Separate email addresses with a comma and no space.

If more than five contacts in your company need to receive new purchase order notifications, you'll need to set up an internal distribution list at your company and configure the distribution list as one of the five email addresses.

SAP Business Network for Procurement & Supply Chain > Administration (Buyer & Supplier Account Administration)